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Laura?Uenver-ThieleEmail author Alan?B.?Woodland Nobuyoshi?Miyajima Tiziana?Boffa?Ballaran Daniel?J.?Frost 《Contributions to Mineralogy and Petrology》2018,173(3):20
Experiments at high pressures and temperatures were carried out (1) to investigate the crystal-chemical behaviour of Fe4O5–Mg2Fe2O5 solid solutions and (2) to explore the phase relations involving (Mg,Fe)2Fe2O5 (denoted as O5-phase) and Mg–Fe silicates. Multi-anvil experiments were performed at 11–20 GPa and 1100–1600 °C using different starting compositions including two that were Si-bearing. In Si-free experiments the O5-phase coexists with Fe2O3, hp-(Mg,Fe)Fe2O4, (Mg,Fe)3Fe4O9 or an unquenchable phase of different stoichiometry. Si-bearing experiments yielded phase assemblages consisting of the O5-phase together with olivine, wadsleyite or ringwoodite, majoritic garnet or Fe3+-bearing phase B. However, (Mg,Fe)2Fe2O5 does not incorporate Si. Electron microprobe analyses revealed that phase B incorporates significant amounts of Fe2+ and Fe3+ (at least ~?1.0 cations Fe per formula unit). Fe-L2,3-edge energy-loss near-edge structure spectra confirm the presence of ferric iron [Fe3+/Fetot?=?~?0.41(4)] and indicate substitution according to the following charge-balanced exchange: [4]Si4+?+?[6]Mg2+?=?2Fe3+. The ability to accommodate Fe2+ and Fe3+ makes this potential “water-storing” mineral interesting since such substitutions should enlarge its stability field. The thermodynamic properties of Mg2Fe2O5 have been refined, yielding H°1bar,298?=???1981.5 kJ mol??1. Solid solution is complete across the Fe4O5–Mg2Fe2O5 binary. Molar volume decreases essentially linearly with increasing Mg content, consistent with ideal mixing behaviour. The partitioning of Mg and Fe2+ with silicates indicates that (Mg,Fe)2Fe2O5 has a strong preference for Fe2+. Modelling of partitioning with olivine is consistent with the O5-phase exhibiting ideal mixing behaviour. Mg–Fe2+ partitioning between (Mg,Fe)2Fe2O5 and ringwoodite or wadsleyite is influenced by the presence of Fe3+ and OH incorporation in the silicate phases. 相似文献
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Serena C. Tarantino Michele Zema Tiziana Boffa Ballaran 《Physics and Chemistry of Minerals》2010,37(10):769-778
The structural evolution of two columbites under pressure, one ferrocolumbite from Raode (Africa) and one manganocolumbite
from Kragero (Norway), has been determined by single-crystal X-ray diffraction. Structural investigations at high pressure
have been carried out on samples which were preliminarily annealed to attain the complete cation-ordered state. For each crystal,
five complete datasets have been collected from room pressure up to ca. 7 GPa. Structure refinements converged to final discrepancy
factors R ranging between 5.2 and 5.8% for both the crystals. Structure refinements of X-ray diffraction data at different pressures
allowed characterisation of the mechanisms by which the columbite structure accommodates variations in pressure. A and B octahedral
volumes in both samples decrease linearly as pressure increases, with a larger compression of the larger A site. The difference
in polyhedral bulk moduli of the A sites for the two samples does not appear to relate directly to the octahedral sizes, the
A site being more compressible in the Fe-rich sample than in the Mn-rich one. By far the most compressible direction in both
the analysed samples is along b. The cations are in fact free to move along this direction, thus allowing the octahedral chains to slide over each other;
this effect is particularly evident in the manganocolumbite sample which shows a steep shortening of interchain A–B distances
along b. 相似文献
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Magnetite is one of the most important end member of iron corrosion products under a reducing environment; therefore, it may be one of the first products interacting with radionuclides in a radioactive waste disposal after the canister failure.Nanocrystalline magnetite was synthetised in the laboratory and its main physico-chemical properties (microstructure, surface area, surface charge) were analysed. The stability of the oxide was also investigated under the experimental conditions used in sorption studies. The sorption behaviour of UVI onto magnetite was analysed under O2- and CO2-free conditions in a wide range of pH, ionic strengths and radionuclide concentrations.The uranyl binding to magnetite is characterised by a sorption edge between pH 4 and 5.5, and sorption was found to be independent on the electrolyte concentration, which indicates the formation of inner sphere complexes. The sorption isotherms showed a linear behaviour up to the saturation of the sorption sites with a Langmuir-type behaviour.One of the aims of this work was to find the simplest model capable to reproduce the experimental data. Sorption data were fitted using a classical approximation (diffuse double layer model), considering only one type of surface site and evaluating two different options: the first one involving two different monodentate complexes, and the second one a single binuclear bidentate complex. A highly satisfactory fit of the experimental data was obtained by both approaches in the range of the experimental conditions investigated. 相似文献
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Dario Dello Iacono Aldo Zollo Maurizio Vassallo Tiziana Vanorio Sebastien Judenherc 《Bulletin of Volcanology》2009,71(3):275-284
In September 2001, an extensive active-seismic investigation (Serapis experiment) was carried out in the Gulfs of Naples and
Pozzuoli, with the aim of investigating and reconstructing the shallow crustal structure of the Campi Flegrei caldera, and
possibly identifying its feeding system at depth. The present study provides a joint analysis of the very shallow seismic
reflection data and tomographic images based on the Serapis dataset. This is achieved by reflection seismic sections obtained
by the 3D data gathering and through refined P-velocity images of the shallowest layer of Pozzuoli Gulf (z < 1,000 m). From the refined Vp model, the overall picture of the velocity distribution confirms the presence of a complex
arc-shaped anomaly that borders the bay offshore. The deeper part of the anomaly (beneath 700 m, with Vp > 3,500 m/s) correlates
with units made up of agglomerate tuffs and interbedded lava, which form the southern edge of the caldera, which was probably
formed following the two large ignimbritic eruptions that marked the evolutionary history of the area under study. The upper
part of the anomaly that tends to split into two parallel arcs is correlated with dikes, volcanic mounds and hydrothermal
alteration zones noted in previous shallow reflection seismic analyses. The depth of the transition between the upper and
lower parts of the anomaly is characterized by an abrupt Vp increase on the one-dimensional (1D) profiles extracted from the
3D tomographic model and by the presence of a strong reflector located at about 0.6/0.7 s Two Way Time (TWT) on Common Mid
Point gathers. The move-out velocity analysis and stack of the P–P and P–S reflections at the layer bottom allowed to estimate
relatively high Vp/Vs values (3.7 ± 0.9). This hypothesis has been tested by a theoretical rock physical modeling of the Vp/Vs
ratio as a function of porosity suggesting that the shallow layer is likely formed by incoherent, water saturated, volcanic
and marine sediments that filled Pozzuoli Bay during the post-caldera activity. 相似文献
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Suman Bhattacharya Tiziana Di Matteo Arthur Kosowsky 《Monthly notices of the Royal Astronomical Society》2008,389(1):34-44
We study the effect of quasar feedback on distributions of baryons in galaxy groups using high-resolution numerical simulations. We use the entropy-conserving gadget code that includes gas cooling and star formation, modified to include a physically based model of quasar feedback. For a sample of 10 galaxy group-sized dark matter haloes with masses in the range of 1–5 × 1013 M⊙ h −1 , star formation is suppressed by more than 50 per cent in the inner regions due to the additional pressure support by quasar feedback, while gas is driven from the inner region towards the outer region of the haloes. As a result, the average gas density is 50 per cent lower in the inner region and 10 per cent higher in the outer region in the simulation, compared to a similar simulation with no quasar feedback. Gas pressure is also higher in the outer region, while temperature and entropy are enhanced in the inner region. The total group gas fraction in the two simulations generally differs by less than 10 per cent. We also find a small change of the total thermal Sunyaev–Zeldovich distortion, leading to 10 per cent changes in the microwave angular power spectrum at angular scales below 2 arcmin. 相似文献
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T. Rossetto N. Peiris A. Pomonis S. M. Wilkinson D. Del Re R. Koo S. Gallocher 《Natural Hazards》2007,42(1):105-124
On December 26, 2004 a great earthquake (M
W 9.3) occurred off the western coast of Sumatra triggering a series of tsunami waves that propagated across the Indian Ocean
causing damage and life loss in 12 countries. This paper summarizes the observations of lifeline performance, building damage
and its distribution, and the social and economic impact of the tsunami made by the Earthquake Engineering Field Investigation
Team (EEFIT) in Thailand and Sri Lanka. EEFIT operates under the umbrella of the UK’s Institution of Structural Engineers.
It is observed that good engineering practice can reduce economic losses, but additional measures are required to reduce risk
to life. 相似文献
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The Peloritani region is one of the most seismically active regions in Italy and, consequently, the quantification of attenuation of the medium plays an important role for seismic risk evaluation. Moreover, it is necessary for the prediction of earth ground motion and future seismic source studies. An in depth analysis has been made here to understand the frequency and lapse time dependence of attenuation characteristics of the region by using the coda of local earthquakes. A regionalization is likewise performed in order to investigate the spatial variation of coda Q across the whole region. Finally, our results are jointly interpreted with those obtained from recently published 3D velocity tomographies for further insights. 相似文献